A pixel structure electrically connected to a data line and a scan line, and including a first and a second active device, a first and a second pixel electrode, and a first and a second capacitance electrode is provided. The first pixel electrode electrically connected to the first active device includes a first and a second electrode block electrically connected to each other. The second pixel electrode electrically connected to the second active device is electrically insulated from the first pixel electrode and separates the first and the second electrode block. The first pixel electrode respectively forms a first and a second capacitor with the first and the second capacitance electrode. The second pixel electrode respectively forms a third and a fourth capacitor with the first and the second capacitance electrode. The first and the second capacitor have different capacitances. The third and the fourth capacitor have different capacitances.