发明申请
US20090156860A1 CATALYST FOR PRODUCING ALPHA, BETA-UNSATURATED CARBOXYLIC ACID AND METHOD FOR PREPARATION THEREOF, AND METHOD FOR PRODUCING ALPHA, BETA-UNSATURATED CARBOXYLIC ACID
有权
用于制备ALPHA,BETA不饱和羧酸的催化剂及其制备方法,以及生产ALPHA,不饱和羧酸的方法
- 专利标题: CATALYST FOR PRODUCING ALPHA, BETA-UNSATURATED CARBOXYLIC ACID AND METHOD FOR PREPARATION THEREOF, AND METHOD FOR PRODUCING ALPHA, BETA-UNSATURATED CARBOXYLIC ACID
- 专利标题(中): 用于制备ALPHA,BETA不饱和羧酸的催化剂及其制备方法,以及生产ALPHA,不饱和羧酸的方法
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申请号: US12388917申请日: 2009-02-19
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公开(公告)号: US20090156860A1公开(公告)日: 2009-06-18
- 发明人: Yuji Fujimori , Wataru Ninomiya , Akio Takeda , Mai Kojima
- 申请人: Yuji Fujimori , Wataru Ninomiya , Akio Takeda , Mai Kojima
- 申请人地址: JP Tokyo
- 专利权人: Mitsubishi Rayon Co., Ltd.
- 当前专利权人: Mitsubishi Rayon Co., Ltd.
- 当前专利权人地址: JP Tokyo
- 优先权: JP2004-033256 20040210; JP2004-033276 20040210; JP2004-233287 20040810
- 主分类号: C07C51/25
- IPC分类号: C07C51/25 ; C07C45/34
摘要:
The object of the present invention is to provide a catalyst which can produce an α,β-unsaturated carboxylic acid through liquid-phase oxidation of an olefin or an α,β-unsaturated aldehyde in good reaction performance, a method for producing the catalyst, and a method for producing an α,β-unsaturated carboxylic acid by using the catalyst. The present invention resides in a catalyst for producing an α,β-unsaturated carboxylic acid, wherein a metal is supported on a carrier with a total pore volume of 0.40 to 1.50 cc/g as measured by nitrogen gas adsorption method, or wherein palladium with an average particle diameter in the range of 1 to 8 nm is supported on the carrier.
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