发明申请
- 专利标题: SEPARATION OF OLEFINS FROM OLEFINS/PARAFFINS MIXED GAS
- 专利标题(中): 来自烯烃/分散体混合气体的烯烃的分离
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申请号: US12593249申请日: 2008-03-28
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公开(公告)号: US20100048971A1公开(公告)日: 2010-02-25
- 发明人: Jong-Nam Kim , Jong-Ho Park , Seong-Jun Lee , Min-Su Ko , Hee Tae Beum , Jongkee Park , Chang Hyun Ko , Sang Sup Han , Soon-Haeng Cho
- 申请人: Jong-Nam Kim , Jong-Ho Park , Seong-Jun Lee , Min-Su Ko , Hee Tae Beum , Jongkee Park , Chang Hyun Ko , Sang Sup Han , Soon-Haeng Cho
- 申请人地址: KR Daejeon KR Seoul
- 专利权人: KOREA INSTITUTE OF ENERGY RESEARCH,SK ENERGY CO., LTD.
- 当前专利权人: KOREA INSTITUTE OF ENERGY RESEARCH,SK ENERGY CO., LTD.
- 当前专利权人地址: KR Daejeon KR Seoul
- 优先权: KR10-2007-0030970 20070329
- 国际申请: PCT/KR2008/001764 WO 20080328
- 主分类号: C07C7/04
- IPC分类号: C07C7/04 ; C07C7/11
摘要:
The present invention relates to a method and an apparatus for the separation of C4 olefins (butene-1, trans-2-butene, cis-2-butene, etc.) and C4 paraffins (normal butane, isobutane, etc.) from a C4 hydrocarbon mixed gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The method of the present invention produces C4 olefins with high purity by introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbent selectively adsorbing olefins to adsorb C4 olefins and to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins adsorbed on the adsorption tower with a desorbent (C5 hydrocarbon, C6 hydrocarbon, etc.), and then separating the C4 olefin and the desorbent by a distillation process. The apparatus of the present invention is composed of several adsorption towers loaded with an adsorbent which selectively adsorb olefins and two distillation towers for the separation of the mixture gases of olefins/desorbents and paraffins/desorbents respectively, The basic operating process of the adsorption tower comprises a adsorption step of selectively adsorbing C4 olefin from the feeding mixture, a C4 olefin rinse step of removing a small amount of C4 paraffins adsorbed together with C4 olefins, and a desorption step of desorbing C4 olefins by using a desorbent, and further comprises a pressure equalization step, a cocurrent depressurization step, and a accumulation pressure step in order to increase the yield and concentration of olefins depending on the operation pressure of the adsorption tower. The desorbent discharged from the process together with olefins or paraffins is separated in the distillation tower and then recycled.
公开/授权文献
- US08436223B2 Separation of olefins from olefins/paraffins mixed gas 公开/授权日:2013-05-07