发明申请
- 专利标题: METHOD FOR HYDRODEHALOGENATION OF ORGANIC HALOGEN COMPOUND
- 专利标题(中): 有机卤化物化合物的氢化方法
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申请号: US12089211申请日: 2006-10-05
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公开(公告)号: US20100130768A1公开(公告)日: 2010-05-27
- 发明人: Koji Sato , Makoto Imai
- 申请人: Koji Sato , Makoto Imai
- 申请人地址: JP Chuo-ku
- 专利权人: Daiichi Sankyo Company, Limited
- 当前专利权人: Daiichi Sankyo Company, Limited
- 当前专利权人地址: JP Chuo-ku
- 优先权: JP2005-292090 20051005
- 国际申请: PCT/JP2006/319948 WO 20061005
- 主分类号: C07C69/74
- IPC分类号: C07C69/74 ; C07C1/26
摘要:
The present invention relates to a hydrodehalogenation method in which a halogen atom on a carbon atom of an organic compound is removed by substituting the halogen atom with a hydrogen atom, and to a method for producing a dehalogenated compound. The hydrodehalogenation method is characterized by including treating an organic compound having a halogen atom on a carbon atom thereof in a solvent with a compound represented by formula (2-1): M2BHpR1q (2-1) or formula (2-2): M3(BHpR1q)2 (2-2) (wherein M2 represents an alkali metal atom; M3 represents an alkaline earth metal atom or a zinc atom; R1 represents a hydrogen atom, a cyano group, a C2-C13 acyloxy group, or a C1-C6 alkoxy group; p is an integer of 1 to 4; q is an integer of 0 to 3; and the sum of p and q is 4) in the presence of a Group VIII metal complex represented by formula (1): M1XmLn (1) (wherein M1 represents a Group VIII metal; X represents a halogen atom; L represents a neutral ligand; m is an integer of 1 or 2; n is an integer of 2 or 3; and the sum of m and n is 4).
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