A method of manufacturing a nanofiber web using an electrospinning method is disclosed. The method comprises the steps of: supplying a polymer solution to the surface of a metal roller 10 with a direct current high voltage applied thereto; spinning the polymer solution supplied to the surface of the metal roller 10 toward a collector 40 of a metal plate with a direct current high voltage applied thereto having a different charge from that of the metal roller 10 to volatilize nanofibers, wherein the collector of the metal plate is located on the horizontal surface of the metal roller 10; and coating the volatilized nanofibers 70 on the collector 40. This method can improve the uniformity of the web, make the management of a production process easier, freely change type of web to be produced, make the maintenance and repair of facilities convenient, and simplify the facilities.