发明申请
- 专利标题: ZSM-5, ITS PREPARATION AND USE IN ETHYLBENZENE DEALKYLATION
- 专利标题(中): ZSM-5,其制备和用于乙二醇处理
-
申请号: US12677009申请日: 2008-09-10
-
公开(公告)号: US20100217057A1公开(公告)日: 2010-08-26
- 发明人: László Domokos , Ralph Haswell , Hong-Xin Li
- 申请人: László Domokos , Ralph Haswell , Hong-Xin Li
- 国际申请: PCT/EP08/61967 WO 20080910
- 主分类号: C07C4/12
- IPC分类号: C07C4/12 ; C01B39/02 ; B01J29/06 ; B01J29/46 ; B01J29/40 ; B01J29/44
摘要:
A new configuration of ZSM-5 is provided whereby the crystals have a higher average silica to alumina ratio at the edges of each crystallite than in the centre as determined from a narrow slit line scan profile obtained from SEM/EDX or TEM/EDX elemental analysis. Such ZSM-5 crystals are obtained by a preparation process using L-tartaric acid. The new configuration ZSM-5 provides significantly reduced xylene losses in ethylbenzene dealkylation, especially when combined with silica as binder, and one or more hydrogenation metals selected from platinum, tin, lead, silver, copper, and nickel. Further advantages are found if used in combination with a small crystal size ZSM-5.
公开/授权文献
- US08574542B2 ZSM-5, its preparation and use in ethylbenzene dealkylation 公开/授权日:2013-11-05
信息查询