发明申请
US20100240846A1 Catalyst component for the polymerization of olefins based on 1,3-diethers
审中-公开
用于基于1,3-二醚的烯烃聚合的催化剂组分
- 专利标题: Catalyst component for the polymerization of olefins based on 1,3-diethers
- 专利标题(中): 用于基于1,3-二醚的烯烃聚合的催化剂组分
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申请号: US12308423申请日: 2007-06-01
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公开(公告)号: US20100240846A1公开(公告)日: 2010-09-23
- 发明人: Gianni Collina , Ofelia Fusco , Benedetta Gaddi , Giampiero Morini , Mario Sacchetti , Gianni Vitale
- 申请人: Gianni Collina , Ofelia Fusco , Benedetta Gaddi , Giampiero Morini , Mario Sacchetti , Gianni Vitale
- 申请人地址: IT Milan
- 专利权人: BASEL POLIOLEFINE ITALIA S.R.L.
- 当前专利权人: BASEL POLIOLEFINE ITALIA S.R.L.
- 当前专利权人地址: IT Milan
- 优先权: EP06115883.8 20060622
- 国际申请: PCT/EP2007/055392 WO 20070601
- 主分类号: C08F4/602
- IPC分类号: C08F4/602 ; C08F4/60
摘要:
Catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and 1,3-diethers as internal donors having an improved balance of properties in terms of activity and morphological stability are obtained by a process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, with a titanium compound having at least a Ti—Cl bond at a reaction temperature ranging from 0° C. to 80° C.; (B) A subsequent step comprising contacting the solid product obtained in (A) with an electron donor ED selected from 1,3 diethers with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.; and (C) A subsequent step comprising reacting the solid product coming from (B) with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.
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