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    Catalyst component for the polymerization of olefins based on 1,3-diethers
    1.
    发明申请
    Catalyst component for the polymerization of olefins based on 1,3-diethers 审中-公开
    用于基于1,3-二醚的烯烃聚合的催化剂组分

    公开(公告)号：US20100240846A1

    公开(公告)日：2010-09-23

    申请号：US12308423

    申请日：2007-06-01

    申请人： Gianni Collina ,  Ofelia Fusco ,  Benedetta Gaddi ,  Giampiero Morini ,  Mario Sacchetti ,  Gianni Vitale

    发明人： Gianni Collina ,  Ofelia Fusco ,  Benedetta Gaddi ,  Giampiero Morini ,  Mario Sacchetti ,  Gianni Vitale

    IPC分类号： C08F4/602 ,  C08F4/60

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/18 ,  C08F2500/24

    摘要： Catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and 1,3-diethers as internal donors having an improved balance of properties in terms of activity and morphological stability are obtained by a process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, with a titanium compound having at least a Ti—Cl bond at a reaction temperature ranging from 0° C. to 80° C.; (B) A subsequent step comprising contacting the solid product obtained in (A) with an electron donor ED selected from 1,3 diethers with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.; and (C) A subsequent step comprising reacting the solid product coming from (B) with a titanium compound having at least a Ti—Cl bond at a temperature higher than 80° C.

    摘要翻译： 通过包括以下步骤的方法获得包含Mg，Ti，卤素和作为内部供体的1,3-二醚作为内部供体具有改善的活性和形态稳定性能平衡的催化剂组分：（A）第一步，包括使 式中MgCl 2（ROH）n的加合物，其中R为C 1 -C 10烷基，n为0.5至6，钛化合物在0℃的反应温度下至少具有Ti-Cl键。 至80℃。 （B）随后的步骤包括使（A）中获得的固体产物与选自1,3二醚的电子给体ED与具有至少Ti-Cl键的钛化合物在高于80℃的温度下接触; 和（C）随后的步骤包括使来自（B）的固体产物与至少具有Ti-Cl键的钛化合物在高于80℃的温度下反应。

    Process for the Preparation of Impact Resistant Propylene Polymer Compositions
    2.
    发明申请
    Process for the Preparation of Impact Resistant Propylene Polymer Compositions 有权
    制备耐冲击丙烯聚合物组合物的方法

    公开(公告)号：US20120083576A1

    公开(公告)日：2012-04-05

    申请号：US13376893

    申请日：2010-06-16

    申请人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    发明人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    IPC分类号： C08J3/00 ,  C08L23/24 ,  C08L23/20 ,  C08L23/16 ,  C08L23/12

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6494

    摘要： A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.

    摘要翻译： 一种制备丙烯聚合物组合物的方法，所述组合物在催化剂体系存在下进行，所述催化剂体系包含（a）平均粒度为15-80μm的固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为50-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚，（b） 烷基铝和任选的（c）外电子给体化合物，并包括以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触; （ii）每克固体催化剂组分（a）预聚合至约0.1至约1000g的聚合物的形成量; （iii）聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iv）在连续步骤中，在气相聚合乙烯混合物 其中R是具有1-10个碳原子的烃基的α-烯烃CH 2 = CHR，以制备所述乙烯共聚物。

    Process for the preparation of impact resistant propylene polymer compositions
    5.
    发明授权
    Process for the preparation of impact resistant propylene polymer compositions 有权
    制备耐冲击丙烯聚合物组合物的方法

    公开(公告)号：US09068028B2

    公开(公告)日：2015-06-30

    申请号：US13376893

    申请日：2010-06-16

    申请人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    发明人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    IPC分类号： C08F10/06 ,  C08F4/651 ,  C08F110/06

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6494

    摘要： A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.

    摘要翻译： 一种制备丙烯聚合物组合物的方法，所述组合物在催化剂体系存在下进行，所述催化剂体系包含（a）平均粒度为15-80μm的固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为50-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚，（b） 烷基铝和任选的（c）外电子给体化合物，并包括以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触; （ii）每克固体催化剂组分（a）预聚合至约0.1至约1000g的聚合物的形成量; （iii）聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iv）在连续步骤中，在气相聚合乙烯混合物 其中R是具有1-10个碳原子的烃基的α-烯烃CH 2 = CHR，以制备所述乙烯共聚物。