The invention relates to a method and device for determining the composition of a fuel mixture made of one first fuel and at least one second fuel for operating an internal combustion engine, wherein said internal combustion engine has a fuel metering apparatus and at least one exhaust gas probe in an exhaust gas channel. According to the method of the invention, it is provided that the fuel mixture is at least temporarily supplied to the exhaust gas probe at least partially uncombusted, and the composition of the fuel mixture is determined from an output signal of the exhaust gas probe. According to the device of the invention, it is provided that the exhaust gas probe is situated proximal to the motor in the direction of the exhaust gas flow before a first catalytic converter, and the fuel mixture can be supplied at least partially uncombusted to the exhaust gas probe at least temporarily. The method allows the precise and reliable determination of the composition of a fuel mixture in internal combustion engines operated in flex fuel operation existing components.