Invention Application
US20110040098A1 Organoactinide-, Organolanthanide-, and OrganoGroup-4-Mediated Hydrothiolation of Terminal Alkynes with Aliphatic, Aromatic and Benzylic Thiols
有权
有机乳剂，有机镧系元素和有机基团4-介导的末端炔烃与脂肪族，芳香族和苄基硫醇的水解
- Patent Title: Organoactinide-, Organolanthanide-, and OrganoGroup-4-Mediated Hydrothiolation of Terminal Alkynes with Aliphatic, Aromatic and Benzylic Thiols
- Patent Title (中): 有机乳剂，有机镧系元素和有机基团4-介导的末端炔烃与脂肪族，芳香族和苄基硫醇的水解
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Application No.: US12856154Application Date: 2010-08-13
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Publication No.: US20110040098A1Publication Date: 2011-02-17
- Inventor: Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
- Applicant: Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
- Main IPC: C07C319/18
- IPC: C07C319/18 ; C07D213/32 ; C07C323/27 ; C07C321/18
Abstract:
An efficient and highly Markovnikov selective organoactinide-, organolanthanide-, and organozirconium-catalyzed addition of aryl, benzyl, and aliphatic thiols to terminal alkynes is described. The corresponding vinyl sulfides are produced with little or no side-products.
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