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1.发明申请ORGANOACTINIDE-, ORGANOLANTHANIDE-, AND ORGANOGROUP-4-MEDIATED HYDROTHIOLATION OF TERMINAL ALKYNES WITH ALIPHATIC, AROMATIC AND BENZYLIC THIOLS 审中-公开ORGANOACTINIDE-，ORGANOLANTHANIDE-和ORGANOGROUP-4-介导的末端烷基酯与芳香，芳香和苯甲醇的氢化公开(公告)号：US20140142319A1
公开(公告)日：2014-05-22
申请号：US14108016
申请日：2013-12-16
Applicant: Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
Inventor： Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
IPC: C07B45/06 , C07D213/32 , C07C319/18
CPC classification number: C07B45/06 , C07C319/18 , C07C323/03 , C07C323/27 , C07C2601/14 , C07C2601/16 , C07D213/32 , C07C321/18 , C07C321/20 , C07C321/22 , C07C321/28
Abstract: An efficient and highly Markovnikov selective organoactinide-, organolanthanide-, and organozirconium-catalyzed addition of aryl, benzyl, and aliphatic thiols to terminal alkynes is described. The corresponding vinyl sulfides are produced with little or no side-products.
Abstract translation: 描述了一种有效和高度的马尔科夫尼科夫选择性有机酸苷，有机镧系元素和有机锆催化的芳基，苄基和脂族硫醇向末端炔烃的加成。 生产相应的乙烯基硫化物很少或没有副产物。
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2.发明授权Organoactinide-, organolanthanide-, and organogroup-4-mediated hydrothiolation of terminal alkynes with aliphatic, aromatic and benzylic thiols 有权有机锕系元素，有机镧系元素和有机基团4介导的末端炔烃与脂族，芳族和苄基硫醇的氢解公开(公告)号：US08609902B2
公开(公告)日：2013-12-17
申请号：US12856154
申请日：2010-08-13
Applicant: Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
Inventor： Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
IPC: C07C381/00
CPC classification number: C07B45/06 , C07C319/18 , C07C323/03 , C07C323/27 , C07C2601/14 , C07C2601/16 , C07D213/32 , C07C321/18 , C07C321/20 , C07C321/22 , C07C321/28
Abstract: An efficient and highly Markovnikov selective organoactinide-, organolanthanide-, and organozirconium-catalyzed addition of aryl, benzyl, and aliphatic thiols to terminal alkynes is described. The corresponding vinyl sulfides are produced with little or no side-products.
Abstract translation: 描述了一种有效和高度的马尔科夫尼科夫选择性有机酸苷，有机镧系元素和有机锆催化的芳基，苄基和脂族硫醇向末端炔烃的加成。 生产相应的乙烯基硫化物很少或没有副产物。
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3.发明申请Organoactinide-, Organolanthanide-, and OrganoGroup-4-Mediated Hydrothiolation of Terminal Alkynes with Aliphatic, Aromatic and Benzylic Thiols 有权有机乳剂，有机镧系元素和有机基团4-介导的末端炔烃与脂肪族，芳香族和苄基硫醇的水解公开(公告)号：US20110040098A1
公开(公告)日：2011-02-17
申请号：US12856154
申请日：2010-08-13
Applicant: Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
Inventor： Tobin J. Marks , Charles J. Weiss , Stephen D. Wobser
IPC: C07C319/18 , C07D213/32 , C07C323/27 , C07C321/18
CPC classification number: C07B45/06 , C07C319/18 , C07C323/03 , C07C323/27 , C07C2601/14 , C07C2601/16 , C07D213/32 , C07C321/18 , C07C321/20 , C07C321/22 , C07C321/28
Abstract: An efficient and highly Markovnikov selective organoactinide-, organolanthanide-, and organozirconium-catalyzed addition of aryl, benzyl, and aliphatic thiols to terminal alkynes is described. The corresponding vinyl sulfides are produced with little or no side-products.
Abstract translation: 描述了一种有效和高度的马尔科夫尼科夫选择性有机酸苷，有机镧系元素和有机锆催化的芳基，苄基和脂族硫醇向末端炔烃的加成。 生产相应的乙烯基硫化物很少或没有副产物。
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