发明申请
- 专利标题: Process For The Preparation of Fluoroolefin Compounds
- 专利标题(中): 氟烯烃化合物的制备方法
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申请号: US13144239申请日: 2010-01-12
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公开(公告)号: US20120022301A1公开(公告)日: 2012-01-26
- 发明人: Pierre-Marie Sedat , Jean-Michel Bossoutrot
- 申请人: Pierre-Marie Sedat , Jean-Michel Bossoutrot
- 申请人地址: FR Colombes
- 专利权人: Arkema France
- 当前专利权人: Arkema France
- 当前专利权人地址: FR Colombes
- 优先权: FR0950157 20090113
- 国际申请: PCT/FR2010/050043 WO 20100112
- 主分类号: C07C17/23
- IPC分类号: C07C17/23
摘要:
The subject of the invention is a process for the preparation of fluoroolefin compounds. It relates more particularly to a process for manufacturing a (hydro)fluoroolefin compound comprising (i) bringing at least one compound comprising from three to six carbon atoms, at least two fluorine atoms and at least one hydrogen atom, provided that at least one hydrogen atom and one fluorine atom are located on adjacent carbon atoms, into contact with potassium hydroxide in a stirred reactor, containing an aqueous reaction medium, equipped with at least one inlet for the reactants and with at least one outlet, in order to give the (hydro)fluoroolefin compound, which is separated from the reaction medium in gaseous form, and potassium fluoride, (ii) bringing the potassium fluoride formed in (i) into contact, in an aqueous medium, with calcium hydroxide in order to give potassium hydroxide and to precipitate calcium fluoride, (iii) separation of the calcium fluoride precipitated in step (ii) from the reaction medium and (iv) optionally, the reaction medium is recycled after optional adjustment of the potassium hydroxide concentration to step (i).
公开/授权文献
- US09018429B2 Process for the preparation of fluoroolefin compounds 公开/授权日:2015-04-28
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