Invention Application
US20120048776A1 HYDRODESULFURIZATION PROCESS WITH SELECTED LIQUID RECYCLE TO REDUCE FORMATION OF RECOMBINANT MERCAPTANS
有权
具有选择性液体回收的减水过程减少重组MERCAPTANS的形成
- Patent Title: HYDRODESULFURIZATION PROCESS WITH SELECTED LIQUID RECYCLE TO REDUCE FORMATION OF RECOMBINANT MERCAPTANS
- Patent Title (中): 具有选择性液体回收的减水过程减少重组MERCAPTANS的形成
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Application No.: US12862845Application Date: 2010-08-25
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Publication No.: US20120048776A1Publication Date: 2012-03-01
- Inventor: Gary G. Podrebarac , Mahesh Subramanyam
- Applicant: Gary G. Podrebarac , Mahesh Subramanyam
- Applicant Address: US TX Pasadena
- Assignee: CATALYTIC DISTILLATION TECHNOLOGIES
- Current Assignee: CATALYTIC DISTILLATION TECHNOLOGIES
- Current Assignee Address: US TX Pasadena
- Main IPC: C10G35/06
- IPC: C10G35/06

Abstract:
Processes for the desulfurization of a cracked naphtha by the reaction of hydrogen with the organic sulfur compounds present in the feed are disclosed. In particular, processes disclosed herein may use one or more catalytic distillation steps followed by further hydrodesulfurization of the naphtha in a fixed bed reactor. It has been found that the formation of recombinant mercaptans in the fixed bed reactor effluent may be reduced or eliminated by reducing the concentration of hydrogen sulfide and/or olefins at the exit of the fixed bed reactor. The reduction or elimination in the formation of recombinant mercaptans may be accomplished by recycling a select portion of the fixed bed reactor effluent to the fixed bed reactor, where the select portion has a relatively low or nil concentration of olefins. Processes disclosed herein may thus facilitate the production of hydrodesulfurized cracked naphthas having a total sulfur content of less than 10 ppm, by weight.
Public/Granted literature
- US08628656B2 Hydrodesulfurization process with selected liquid recycle to reduce formation of recombinant mercaptans Public/Granted day:2014-01-14
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