-
公开(公告)号:US11866389B1
公开(公告)日:2024-01-09
申请号:US17939281
申请日:2022-09-07
发明人: Yaming Jin , Ziyauddin S. Qureshi , Abdullah M. Aitani , Omer Refa Koseoglu , Mohammad Naseem Akhtar , Hassan Saeed Al-Awad Alasiri
IPC分类号: B01J29/40 , C07C2/42 , B01J23/06 , B01J23/00 , B01J35/10 , B01J37/00 , B01J37/04 , B01J37/08 , C10G35/06 , C10G35/095
CPC分类号: C07C2/42 , B01J23/00 , B01J23/06 , B01J29/405 , B01J35/1042 , B01J35/1047 , B01J37/0018 , B01J37/04 , B01J37/088 , C10G35/06 , C10G35/095 , C07C2523/06 , C07C2523/08 , C07C2529/04 , C07C2529/40 , C10G2300/1037 , C10G2300/70
摘要: According to embodiments, a process of forming a catalyst for aromatizing hydrocarbons may include enhancing a mesoporosity of a zeolite support by a base-leaching treatment, an acid-leaching treatment, or both to form a zeolite support having enhanced mesoporosity, mixing the zeolite support having enhanced mesoporosity with a solution containing zinc or gallium to disperse the zinc or gallium on the zeolite support having enhanced mesoporosity, and calcining the zeolite support having enhanced mesoporosity with zinc or gallium dispersed thereon to form a zinc- or gallium-doped zeolite catalyst having a mesopore volume of greater than 0.09 cm3/g and less than 0.20 cm3/g.
-
公开(公告)号:US20230365878A1
公开(公告)日:2023-11-16
申请号:US18314613
申请日:2023-05-09
申请人: PHILLIPS 66 COMPANY
CPC分类号: C10G67/16 , C10G50/00 , C10G35/065 , C10G2400/02 , C10G2300/30 , C10G2300/1081
摘要: Methods that increase production of a liquid transportation fuel blend component by utilizing C5 hydrocarbon streams taken from both a refinery naphtha stream and an NGL fractionator pentanes plus stream. A high vapor pressure pentane fraction from the NGL fractionator is separated to remove isopentane and produce lower vapor pressure commodity natural gasoline. A refinery naphtha stream (that is optionally an FCC naphtha stream) is separated to produce a C5 olefins stream that is then oligomerized to produce an upgraded stream having lower vapor pressure and higher octane rating, then combined with the remainder of the naphtha stream as well as the isopentane stream to produce a gasoline blend component that meets specifications for vapor pressure and octane rating.
-
公开(公告)号:US11529617B2
公开(公告)日:2022-12-20
申请号:US16991540
申请日:2020-08-12
发明人: Ryan W. Snell
摘要: Provided herein are catalyst supports, catalyst systems, and methods for making catalyst supports, catalyst systems, and performing chemical reactions with the catalyst systems. The catalyst supports include a zeolite and a binder including non-sodium counterions, such as ammonium counterions and/or potassium counterions. The catalyst systems include the catalyst supports and a catalytic material. The catalyst systems may be used to perform chemical reactions, including reactions of one or more hydrocarbons.
-
4.
公开(公告)号:US11465950B2
公开(公告)日:2022-10-11
申请号:US17011008
申请日:2020-09-03
发明人: Yaming Jin , Ziyauddin S. Qureshi , Abdullah M. Aitani , Omer Refa Koseoglu , Mohammad Naseem Akhtar , Hassan Saeed Al-Awad Alasiri
IPC分类号: C07C2/42 , B01J23/06 , B01J23/08 , B01J29/40 , B01J35/10 , B01J37/00 , B01J37/04 , B01J37/08 , C10G35/06 , C10G35/095
摘要: According to embodiments, a process for aromatizing hydrocarbons may include contacting the hydrocarbons with a zinc- or gallium-doped ZSM-5 catalyst having a mesopore volume of greater than 0.09 cm3/g. Contacting the hydrocarbons with the catalyst causes a least a portion of the hydrocarbons to undergo chemical reactions to form aromatic hydrocarbons.
-
公开(公告)号:US11097262B2
公开(公告)日:2021-08-24
申请号:US15958394
申请日:2018-04-20
发明人: Veera Venkata Ramakrishna Tammana , Raed Hasan Abudawoud , Ahmad A. Jazzar , Ahmad Al Mahdi , Thamer A. Mohammad
IPC分类号: B01J29/04 , B01J37/00 , B01J37/02 , B01J37/08 , B01J35/02 , B01J35/10 , B01J29/22 , B01J29/44 , B01J29/48 , C10G35/06 , B01J29/26 , C01B39/02 , B01J29/46 , C07C6/12 , B01J37/18 , C07C15/08 , C07C15/06 , B01J29/24 , C07C15/04 , B01J29/80 , B01J29/70
摘要: A method of producing a hierarchical zeolite composite catalyst. The method including dissolving, in an alkaline solution and in the presence of a surfactant, a catalyst precursor comprising mesoporous zeolite to yield a dissolved zeolite solution, where the mesoporous zeolite comprises large pore mordenite and medium pore ZSM-5. The method also including condensing the dissolved zeolite solution to yield a solid zeolite composite from the dissolved zeolite solution and heating the solid zeolite composite to remove the surfactant. The method further including impregnating the solid zeolite composite with one or more active metals selected from the group consisting of molybdenum, platinum, rhenium, nickel, and combinations thereof to yield impregnated solid zeolite composite and calcining the impregnated solid zeolite composite to produce the hierarchical zeolite composite catalyst. The hierarchical zeolite composite catalyst has a mesostructure comprising at least one disordered mesophase and at least one ordered mesophase.
-
6.
公开(公告)号:US11078431B2
公开(公告)日:2021-08-03
申请号:US16715555
申请日:2019-12-16
申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals Ltd. , Japan Cooperation Center, Petroleum
摘要: The present disclosure relates to a process for the deolefinization of hydrocarbon streams through an aromatic alkylation reaction by olefins, using a catalyst containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.
-
公开(公告)号:US11046899B2
公开(公告)日:2021-06-29
申请号:US16592591
申请日:2019-10-03
摘要: Systems and methods include an aromatics complex (ARC), the ARC in fluid communication with a naphtha reforming unit (NREF) and operable to receive a reformate stream produced by the NREF, and the ARC further operable to separate the reformate stream into a gasoline pool stream, an aromatics stream, and an aromatic bottoms stream; and a hydrodearylation unit operable to receive heavy, non-condensed, alkyl-bridged, multi-aromatic compounds from the aromatic bottoms stream, the hydrodearylation unit further operable to hydrogenate and hydrocrack the heavy, non-condensed, alkyl-bridged, multi-aromatic compounds to produce a stream suitable for recycle to the NREF or the reformate stream, where the hydrodearylation unit is further operable to receive hydrogen produced in the NREF.
-
8.
公开(公告)号:US20210179949A1
公开(公告)日:2021-06-17
申请号:US16715555
申请日:2019-12-16
申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals Ltd. , Japan Cooperation Center. Petroleum
摘要: The present disclosure relates to a process for the deolefinization of hydrocarbon streams through an aromatic alkylation reaction by olefins, using a catalyst containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.
-
公开(公告)号:US10899973B1
公开(公告)日:2021-01-26
申请号:US16292096
申请日:2019-03-04
申请人: TDA Research, Inc.
摘要: The present invention provides a steam reforming process for heavy oil or hydrocarbons using a circulating fluidized bed reactor, the process having a reforming step and a regeneration step, wherein the reforming step and the regeneration step comprise a fluidized reactor containing a fluidizable nickel-containing reforming catalyst and produce hydrogen as a product of the reforming bed. The invention produces high purity hydrogen in the synthesis gas product stream and avoids irreversible fouling on the catalyst.
-
公开(公告)号:US20190338201A1
公开(公告)日:2019-11-07
申请号:US16401595
申请日:2019-05-02
发明人: Zan Liu , Peter Loezos , Jackeline Medina , Romain Lemoine
摘要: A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.
-
-
-
-
-
-
-
-
-