发明申请
- 专利标题: Process for the Preparation of Impact Resistant Propylene Polymer Compositions
- 专利标题(中): 制备耐冲击丙烯聚合物组合物的方法
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申请号: US13376893申请日: 2010-06-16
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公开(公告)号: US20120083576A1公开(公告)日: 2012-04-05
- 发明人: Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Francesca Verrocchio
- 申请人: Gianni Collina , Marco Ciarafoni , Ofelia Fusco , Benedetta Gaddi , Monica Galvan , Giampiero Morini , Roberto Pantaleoni , Francesca Verrocchio
- 申请人地址: IT Milano
- 专利权人: BASELL POLIOLEFINE ITALIA S.R.L.
- 当前专利权人: BASELL POLIOLEFINE ITALIA S.R.L.
- 当前专利权人地址: IT Milano
- 优先权: EP09163192.9 20090619
- 国际申请: PCT/EP2010/058437 WO 20100616
- 主分类号: C08J3/00
- IPC分类号: C08J3/00 ; C08L23/24 ; C08L23/20 ; C08L23/16 ; C08L23/12
摘要:
A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.
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