A process for manufacturing stand-alone thin films is provided. The process includes providing a substrate, depositing a carbon-containing sacrificial layer onto the substrate and the depositing a thin film onto the carbon-containing sacrificial layer. Thereafter, the substrate, carbon-containing sacrificial layer and thin film structure are exposed to oxygen at an elevated temperature. The oxygen reacts with the carbon-containing sacrificial layer to produce carbon dioxide and remove carbon from the sacrificial layer, thereby generally burning away the sacrificial layer and affording for an intact stand-alone thin film to separate from the substrate.