A communication control system includes an electronic device and a communication apparatus paired with the electronic device. The electronic device includes an input unit, a first BLUETOOTH unit, and a dialing control module. The input unit generates commands in response to operations of a user. The dialing control module generates dial information when a dialing command is received, and controls the first BLUETOOTH unit to transmit the dial information to the communication apparatus. The communication apparatus includes a wireless communication unit, a second BLUETOOTH unit, and a dialing module. The dialing module controls the wireless communication unit to dial according to the dial information. The dialing module also controls the second BLUETOOTH unit to transmit real-time dial information and voice signals of the user to the electronic device. A related method is also provided.