发明申请
- 专利标题: PROCESS FOR PREPARING LINEAR alpha-OLEFINS
- 专利标题(中): 制备线性α-烯烃的方法
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申请号: US13576414申请日: 2011-01-13
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公开(公告)号: US20120330078A1公开(公告)日: 2012-12-27
- 发明人: Karl Heinz Hofmann , Hans Jorg Zander , Anton Wellenhofer , Wolfgang Muller , Anina Wohl
- 申请人: Karl Heinz Hofmann , Hans Jorg Zander , Anton Wellenhofer , Wolfgang Muller , Anina Wohl
- 申请人地址: DE Muenchen
- 专利权人: LINDE AKTIENGESELLSCHAFT
- 当前专利权人: LINDE AKTIENGESELLSCHAFT
- 当前专利权人地址: DE Muenchen
- 优先权: DE102010006589.7 20100202
- 国际申请: PCT/EP2011/000131 WO 20110113
- 主分类号: C07C2/08
- IPC分类号: C07C2/08
摘要:
The invention relates to a process for preparing linear α-olefins, wherein ethylene 1a is conducted into the oligomerization reactor 2 in the liquid phase. The oligomerization reactor 2 has a mechanical stirrer 2a in order to ensure optimal mixing of the liquid ethylene and of the catalyst in the liquid phase. From the top of the oligomerization reactor 2, vaporized ethylene is drawn off together with light α-olefins and a small proportion of the organic solvent. The gas mixture drawn off from the top of the reactor 2 is condensed together with gaseous fresh ethylene 7 by means of heat exchanger 3 and separator 4. The liquid phase drawn off from the separator 4 is conducted by means of circulation pump 5a as liquid ethylene input 1a back into the oligomerization reactor 2. The liquid products of the oligomerization reaction are drawn off 8 laterally from the base of the reactor 2.
公开/授权文献
- US09896391B2 Process for preparing linear α-olefins 公开/授权日:2018-02-20
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