发明申请
US20130046118A1 METHOD FOR PRODUCING OPTICALLY ACTIVE, RACEMIC MENTHOL
审中-公开
用于生产光学活性的,法定的MENTHOL的方法
- 专利标题: METHOD FOR PRODUCING OPTICALLY ACTIVE, RACEMIC MENTHOL
- 专利标题(中): 用于生产光学活性的,法定的MENTHOL的方法
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申请号: US13658003申请日: 2012-10-23
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公开(公告)号: US20130046118A1公开(公告)日: 2013-02-21
- 发明人: Gunnar Heydrich , Gabriele Gralla , Matthias Rauls , Joachim Schmidt-Leithoff , Klaus Ebel , Wolfgang Krause , Steffen Oehlenschläger , Christoph Jäkel , Marko Friedrich , Eike Johannes Bergner , Nawid Kashani-Shirazi , Rocco Paciello
- 申请人: Gunnar Heydrich , Gabriele Gralla , Matthias Rauls , Joachim Schmidt-Leithoff , Klaus Ebel , Wolfgang Krause , Steffen Oehlenschläger , Christoph Jäkel , Marko Friedrich , Eike Johannes Bergner , Nawid Kashani-Shirazi , Rocco Paciello
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP07122036.2 20071130
- 主分类号: C07C29/17
- IPC分类号: C07C29/17
摘要:
The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method comprises the following steps a.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.
公开/授权文献
- US09988331B2 Method for producing optically active, racemic menthol 公开/授权日:2018-06-05
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