发明申请
- 专利标题: Oxidation of Alkylbenzenes
- 专利标题(中): 烷基苯的氧化
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申请号: US13817239申请日: 2011-08-16
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公开(公告)号: US20130211036A1公开(公告)日: 2013-08-15
- 发明人: Jihad M. Dakka , Edmund J. Mozeleski , Charles Morris Smith , Christopher L. Becker , Stephen Zushma
- 申请人: Jihad M. Dakka , Edmund J. Mozeleski , Charles Morris Smith , Christopher L. Becker , Stephen Zushma
- 申请人地址: US TX Baytown
- 专利权人: ExxonMobil Chemical Company - Law Technology
- 当前专利权人: ExxonMobil Chemical Company - Law Technology
- 当前专利权人地址: US TX Baytown
- 国际申请: PCT/US2011/047840 WO 20110816
- 主分类号: C07C407/00
- IPC分类号: C07C407/00 ; C07C37/08 ; C07C249/08 ; C07D223/10 ; C07C51/16 ; C07C45/53 ; C07C37/11
摘要:
A process for oxidizing a composition comprising contacting an alkylbenzene of the general formula (I): where R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, wherein R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, the cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group; and (ii) about 0.05 wt % to about 5 wt % of phenol, with oxygen in the presence of a catalyst containing a cyclic imide having the general formula (II): wherein X represents an oxygen atom, a hydroxyl group, or an acyloxy group under conditions effective to convert at least a portion of the alkylbenzene to a hydroperoxide.
公开/授权文献
- US08921610B2 Oxidation of alkylbenzenes 公开/授权日:2014-12-30
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