According to the present invention, provided is a liquid crystal display device in which a polymer layer having a stable alignment regulating force is formed. The liquid crystal display device according to the present invention includes a liquid crystal cell that includes a pair of substrates and a liquid crystal layer which is held between the pair of substrates, in which at least one substrate of the pair of substrates includes an electrode, an undercoat film which is formed on a liquid crystal layer side of the electrode, and a polymer layer which is formed on a liquid crystal layer side of the undercoat film and controls the alignment of liquid crystal molecules adjacent to the polymer layer, the undercoat film is formed of a photoactive material, the polymer layer is formed by polymerization of a monomer added to the liquid crystal layer, and the liquid crystal layer contains liquid crystal molecules having, in a molecular structure thereof, a multiple bond other than conjugated double bonds of a benzene ring.