The present invention provides polycarbonate polyol compositions with improved characteristics. Such polycarbonate polyol compositions are useful in thermosetting applications for the production of coatings for consumer products. The present invention provides compositions having such improved characteristics, in particular, polycarbonate polyol compositions having a glass transition temperature (Tg) from about −20° C. to about 60° C., from about −20° C. to about 50° C., or from about 0° C. to about 30° C., are particularl useful in thermosetting applications. In some embodiments, polycarbonate polyol compositions have a Tg from about −20° C. to about 3° C. In some embodiments, polycarbonate polyol compositions have a Tg from about 0° C. to about 50° C., from about 0° C. to about 50° C., or from about 10 “C. to about 40° C.