发明申请
US20140011090A1 NICKEL MANGANESE COMPOSITE HYDROXIDE PARTICLES AND MANUFACTURING METHOD THEREOF, CATHODE ACTIVE MATERIAL FOR A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND MANUFACTURING METHOD THEREOF, AND A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
有权
镍锰复合氢氧化物颗粒及其制造方法,用于非水电解质二次电池的阴极活性材料及其制造方法和非水电解质二次电池
- 专利标题: NICKEL MANGANESE COMPOSITE HYDROXIDE PARTICLES AND MANUFACTURING METHOD THEREOF, CATHODE ACTIVE MATERIAL FOR A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND MANUFACTURING METHOD THEREOF, AND A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
- 专利标题(中): 镍锰复合氢氧化物颗粒及其制造方法,用于非水电解质二次电池的阴极活性材料及其制造方法和非水电解质二次电池
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申请号: US13820110申请日: 2011-03-28
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公开(公告)号: US20140011090A1公开(公告)日: 2014-01-09
- 发明人: Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
- 申请人: Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
- 国际申请: PCT/JP2011/057694 WO 20110328
- 主分类号: C30B7/14
- IPC分类号: C30B7/14 ; H01M10/0525 ; H01M4/525 ; H01M4/04 ; H01M4/36 ; H01M4/505
摘要:
Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.