发明申请
US20140220349A1 METAL NICKEL-IMIDAZOLATE CHIRAL NANO CLATHRATE COMPLEX AND PREPARATION METHOD THEREOF
有权
金属镍 - 咪唑烷基合成纳米复合物及其制备方法
- 专利标题： METAL NICKEL-IMIDAZOLATE CHIRAL NANO CLATHRATE COMPLEX AND PREPARATION METHOD THEREOF
- 专利标题（中）： 金属镍 - 咪唑烷基合成纳米复合物及其制备方法
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申请号： US14343235申请日： 2011-09-14
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公开(公告)号： US20140220349A1公开(公告)日： 2014-08-07
- 发明人: Dan LI , Xiaoping Zhou , Jie Liu
- 申请人： Dan LI , Xiaoping Zhou , Jie Liu
- 申请人地址： US NE Culbertson
- 专利权人： Golight, Inc.
- 当前专利权人： Golight, Inc.
- 当前专利权人地址： US NE Culbertson
- 优先权： CN201110263178.1 20110907
- 国际申请： PCT/CN2011/079647 WO 20110914
- 主分类号： C07F15/04
- IPC分类号： C07F15/04
摘要：
The present invention discloses a metal nickel-imidazolate chiral nano clathrate complex and preparation method thereof. The new type of metal nickel-imidazolate chiral nano clathrate complex of the present invention has the following chemical formula: [Ni14(Im)24].4NO3, in which Im is N-1-methyl-(4-imidazole) methylene imine. The complex can be obtained directly from a reaction of starting materials or prepared through first initiating a reaction between the compound ligand Im and a nickel salt under solvothermal conditions, and the complex obtained is of higher purity. The nano clathrate complex of the present invention has single chirality, and higher thermal stability, and thus has potential application in chiral catalytic materials.
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