A scanning module structure includes an optical reflective casing, a light-emitting element, and an optical sensing module. The optical reflective casing includes plural fixed tilting structures and plural reflective aluminum sheets. The plural fixed tilting structures are integrally formed with the optical reflective casing. The plural reflective aluminum sheets are disposed on corresponding fixed tilting structures. The light-emitting element is used for emitting a light beam. The light beam is reflected by the plural reflective aluminum sheets. When the scanning module structure is enabled, the light beam emitted by the light-emitting element is projected onto a document. After the light beam is reflected by the document, the light beam is introduced into the optical sensing module. The light beam is sequentially reflected by the plural reflective aluminum sheets, and then projected onto the optical sensing module. Consequently, a document image corresponding to the document is generated.