发明申请
- 专利标题: PROCESS FOR THE PREPARATION OF POLYPROPYLENE WITH IMPROVED PRODUCTIVITY
- 专利标题(中): 制备具有改善生产力的聚丙烯的方法
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申请号: US14418808申请日: 2013-07-30
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公开(公告)号: US20150191556A1公开(公告)日: 2015-07-09
- 发明人: Wolfgang Neissl , Dietrich Gloger , Thomas Horill , Martina Sandholzer , Gregory Potter
- 申请人: BOREALIS AG
- 优先权: EP12179546.2 20120807
- 国际申请: PCT/EP2013/065945 WO 20130730
- 主分类号: C08F10/06
- IPC分类号: C08F10/06
摘要:
A process for the preparation of a polypropylene in a sequential polymerization process including a pre-polymerization reactor and at least two polymerization reactors connected in series. The polymerization in the at least two polymerization reactors takes place in the presence of a Ziegler-Natta catalyst. The Ziegler-Natta catalyst includes (a) a pro-catalyst that has a compound of a transition metal, a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, (b) a co-catalyst, and (c) an external donor. The Ziegler-Natta catalyst is present in the pre-polymerization reactor. Ethylene and propylene are fed to the pre-polymerization reactor in a feed rate ratio of 0.5 to 10.0 g/kg.
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