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    Process for the preparation of polypropylene with improved productivity
    2.
    发明授权
    Process for the preparation of polypropylene with improved productivity 有权
    生产率提高的聚丙烯制备方法

    公开(公告)号：US09512246B2

    公开(公告)日：2016-12-06

    申请号：US14418808

    申请日：2013-07-30

    Applicant: Borealis AG

    Inventor： Wolfgang Neissl ,  Dietrich Gloger ,  Thomas Horill ,  Martina Sandholzer ,  Gregory Potter

    IPC: C08F10/06 ,  C08F210/06 ,  C08F2/00 ,  C08F4/654 ,  C08F2/14

    CPC classification number: C08F10/06 ,  C08F2/001 ,  C08F210/06 ,  C08F4/6543 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6492

    Abstract: A process for the preparation of a polypropylene in a sequential polymerization process including a pre-polymerization reactor and at least two polymerization reactors connected in series. The polymerization in the at least two polymerization reactors takes place in the presence of a Ziegler-Natta catalyst. The Ziegler-Natta catalyst includes (a) a pro-catalyst that has a compound of a transition metal, a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, (b) a co-catalyst, and (c) an external donor. The Ziegler-Natta catalyst is present in the pre-polymerization reactor. Ethylene and propylene are fed to the pre-polymerization reactor in a feed rate ratio of 0.5 to 10.0 g/kg.

    Abstract translation: 一种在顺序聚合方法中制备聚丙烯的方法，包括预聚合反应器和至少两个串联的聚合反应器。 在至少两个聚合反应器中的聚合在齐格勒 - 纳塔催化剂存在下进行。 齐格勒 - 纳塔催化剂包括（a）具有过渡金属化合物的前催化剂，金属选自元素周期表第1至3族之一的金属化合物（IUPAC）和内部 电子给体，（b）助催化剂，和（c）外部供体。 齐格勒 - 纳塔催化剂存在于预聚合反应器中。 乙烯和丙烯以0.5至10.0g / kg的进料速率比进料到预聚合反应器中。

    Tiger stripe modifier
    3.
    发明授权
    Tiger stripe modifier 有权
    虎纹修饰符

    公开(公告)号：US09388304B2

    公开(公告)日：2016-07-12

    申请号：US14443797

    申请日：2013-11-28

    Applicant: Borealis AG

    Inventor： Michael Tranninger ,  Georg Grestenberger ,  Martina Sandholzer ,  Simon Schwarzengerger ,  Susanne Kahlen ,  Gregory Potter

    IPC: C08L23/12 ,  C08L23/16

    CPC classification number: C08L23/12 ,  C08L23/16 ,  C08L2205/02 ,  C08L2207/02 ,  C08L23/14 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08F4/6545 ,  C08F4/6465 ,  C08F4/6492

    Abstract: Tiger stripe modifier being a heterophasic polypropylene composition having a melt flow rate MFR2 (230° C.) in the range of 0.5 to 20 g/10 min and comprises a propylene homopolymer and an elastomeric propylene copolymer, wherein said propylene homopolymer has a melt flow rate MFR2 (230° C.) in the range of above 10 to 300 g/10 min; the xylene cold soluble fraction of the heterophasic polypropylene composition has an intrinsic viscosity in the range of more than 2.5 to below 11.0 dl/g; and the comonomer content of the xylene cold soluble fraction of the heterophasic polypropylene composition is in the range of 10.0 to 25.0 wt.-%; wherein further the heterophasic polypropylene composition fulfills the inequation (I) 0.3≧(0.241×C)-(1.14×IV) (I) wherein C is the comonomer content of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1), and IV is the intrinsic viscosity of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1).

    Abstract translation: 老虎条纹改性剂是熔体流动速率MFR 2（230℃）在0.5-20g / 10min范围内的多相聚丙烯组合物，包含丙烯均聚物和弹性体丙烯共聚物，其中所述丙烯均聚物具有熔体流动 在10至300g / 10min范围内的MFR 2（230℃）的速率; 多相聚丙烯组合物的二甲苯冷可溶部分的特性粘度在大于2.5至低于11.0dl / g的范围内; 并且多相聚丙烯组合物的二甲苯冷可溶部分的共聚单体含量在10.0至25.0重量％的范围内; 其中异相聚丙烯组合物还满足不等式（I）0.3≥（0.241×C） - （1.14×IV）（I）其中C是多相聚丙烯组合物的二甲苯冷可溶（XCS）级分的共聚单体含量（HECO1 ），IV是异相聚丙烯组合物（HECO1）的二甲苯冷可溶（XCS）级分的特性粘度。

    PROCESS FOR THE PREPARATION OF POLYPROPYLENE WITH IMPROVED PRODUCTIVITY
    6.
    发明申请
    PROCESS FOR THE PREPARATION OF POLYPROPYLENE WITH IMPROVED PRODUCTIVITY 有权
    制备具有改善生产力的聚丙烯的方法

    公开(公告)号：US20150191556A1

    公开(公告)日：2015-07-09

    申请号：US14418808

    申请日：2013-07-30

    Applicant: BOREALIS AG

    Inventor： Wolfgang Neissl ,  Dietrich Gloger ,  Thomas Horill ,  Martina Sandholzer ,  Gregory Potter

    IPC: C08F10/06

    CPC classification number: C08F10/06 ,  C08F2/001 ,  C08F210/06 ,  C08F4/6543 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6492

    Abstract: A process for the preparation of a polypropylene in a sequential polymerization process including a pre-polymerization reactor and at least two polymerization reactors connected in series. The polymerization in the at least two polymerization reactors takes place in the presence of a Ziegler-Natta catalyst. The Ziegler-Natta catalyst includes (a) a pro-catalyst that has a compound of a transition metal, a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, (b) a co-catalyst, and (c) an external donor. The Ziegler-Natta catalyst is present in the pre-polymerization reactor. Ethylene and propylene are fed to the pre-polymerization reactor in a feed rate ratio of 0.5 to 10.0 g/kg.

    Abstract translation: 一种在顺序聚合方法中制备聚丙烯的方法，包括预聚合反应器和至少两个串联的聚合反应器。 在至少两个聚合反应器中的聚合在齐格勒 - 纳塔催化剂存在下进行。 齐格勒 - 纳塔催化剂包括（a）具有过渡金属化合物的前催化剂，金属选自元素周期表第1至3族之一的金属化合物（IUPAC）和内部 电子给体，（b）助催化剂，和（c）外部供体。 齐格勒 - 纳塔催化剂存在于预聚合反应器中。 乙烯和丙烯以0.5至10.0g / kg的进料速率比进料到预聚合反应器中。

    PROCESS FOR THE PREPARATION OF POLYPROPYLENE WITH IMPROVED PRODUCTIVITY
    8.
    发明申请
    PROCESS FOR THE PREPARATION OF POLYPROPYLENE WITH IMPROVED PRODUCTIVITY 有权
    制备具有改善生产力的聚丙烯的方法

    公开(公告)号：US20150152203A1

    公开(公告)日：2015-06-04

    申请号：US14416121

    申请日：2013-07-30

    Applicant: Borealis AG

    Inventor： Wolfgang Neissl ,  Dietrich Gloger ,  Thomas Horill ,  Martina Sandholzer ,  Gregory Potter

    IPC: C08F110/06

    CPC classification number: C08F110/06 ,  C08F10/06 ,  C08L23/14 ,  C08L2205/025 ,  C08F210/06 ,  C08F2/001 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6543 ,  C08F4/6492 ,  C08F210/16 ,  C08L23/12

    Abstract: A process for the preparation of a polypropylene in a sequential polymerization process including at least two polymerization reactors connected in series. The polymerization takes place in the presence of a Ziegler-Natta catalyst, and said Ziegler-Natta catalyst includes (a) a pro-catalyst that has a compound of a transition metal, a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, (b) a co-catalyst, and (c) an external donor. The ratio of catalyst feed rate to propylene feed rate in the first polymerization reactor is 1.0 to 4.5 q/t.

    Abstract translation: 一种在顺序聚合方法中制备聚丙烯的方法，包括至少两个串联连接的聚合反应器。 聚合在齐格勒 - 纳塔催化剂存在下进行，所述齐格勒 - 纳塔催化剂包括（a）具有过渡金属化合物的前催化剂，金属的化合物，其金属选自 元素周期表（IUPAC）的1至3族，以及内部电子给体，（b）助催化剂和（c）外部给体。 第一聚合反应器中催化剂进料速率与丙烯进料速率的比为1.0-4.5q / t。

    TIGER STRIPE MODIFIER
    10.
    发明申请
    TIGER STRIPE MODIFIER 审中-公开

    公开(公告)号：US20160304709A1

    公开(公告)日：2016-10-20

    申请号：US14442220

    申请日：2013-11-28

    Applicant: BOREALIS AG

    Inventor： Michael Tranninger ,  Georg Grestenberger ,  Martina Sandholzer ,  Simon Schwarzengerger ,  Susanne Kahlen ,  Gregory Potter

    IPC: C08L23/12

    CPC classification number: C08L23/12 ,  C08L2205/02 ,  C08L2207/02 ,  C08L23/14 ,  C08L23/16 ,  C08F210/06 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F110/06

    Abstract: Tiger stripe modifier being a heterophasic polypropylene composition comprising a propylene homopolymer and an elastomeric propylene copolymer, wherein said propylene homopolymer has a melt flow rate MFR2 (230° C.) in the range of above 70 to 300 g/l Omin; the xylene cold soluble fraction of the heterophasic polypropylene composition has an intrinsic viscosity in the range of more than 4.0 to below 12.0 dl/g; and the comonomer content of the xylene cold soluble fraction of the heterophasic polypropylene composition is in the range of 20.0 to 60.0 wt.-%; wherein further the heterophasic polypropylene composition fulfills the inequation (I) 0.30≧(0.241×C)−(1.14×IV) (I) wherein C is the comonomer content of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1), and IV is the intrinsic viscosity of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1).

    Abstract translation: Tiger条纹改性剂是包含丙烯均聚物和弹性体丙烯共聚物的多相聚丙烯组合物，其中所述丙烯均聚物的熔体流动速率MFR 2（230℃）在70-300g / l Omin范围内; 多相聚丙烯组合物的二甲苯冷可溶部分的特性粘度在大于4.0至低于12.0dl / g的范围内; 并且多相聚丙烯组合物的二甲苯冷可溶部分的共聚单体含量在20.0至60.0重量％的范围内; 其中进一步的多相聚丙烯组合物满足不等式（I）0.30≥（0.241×C） - （1.14×IV）（I）其中C是多相聚丙烯组合物的二甲苯冷可溶（XCS）级分的共聚单体含量（HECO1 ），IV是异相聚丙烯组合物（HECO1）的二甲苯冷可溶（XCS）级分的特性粘度。

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