发明申请
- 专利标题: RUTHENIUM-DIAMINE COMPLEXES AND METHOD FOR PRODUCING OPTICALLY ACTIVE COMPOUNDS
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申请号: US14940643申请日: 2015-11-13
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公开(公告)号: US20160067696A1公开(公告)日: 2016-03-10
- 发明人: Taichiro Touge , Hideki Nara , Tomohiko Hakamada
- 申请人: Takasago International Corporation
- 优先权: JP2010-189738 20100826
- 主分类号: B01J31/18
- IPC分类号: B01J31/18 ; C07C29/143 ; C07C209/52 ; C07C253/30 ; C07D311/22 ; C07F15/00 ; C07D307/42
摘要:
Provided is a catalyst for asymmetric reduction, which can be produced by a convenient and safe production method, has a strong catalytic activity, and has excellent stereoselectivity. The present invention relates to a ruthenium complex represented by the following formula (1): wherein R1 represents an alkyl group or the like; Y represents a hydrogen atom; X represents a halogen atom or the like; j and k each represent 0 or 1; R2 and R3 each represent an alkyl group or the like; R11 to R19 each represent a hydrogen atom, an alkyl group or the like; Z represents oxygen or sulfur; n1 represents 1 or 2; and n2 represents an integer from 1 to 3, a method for producing the ruthenium complex, a catalyst for asymmetric reduction formed from the ruthenium complex, and methods for selectively producing an optically active alcohol and an optically active amine using the catalyst for asymmetric reduction.
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