Invention Application
US20160083909A1 FINELY DIVIDED, STARCH-CONTAINING POLYMER DISPERSIONS, PROCESSES FOR THEIR PREPARATION AND USE AS SIZES IN PAPERMAKING 审中-公开
精细分散,含淀粉的聚合物分散体,其制备方法和用于造纸中的尺寸

  • Patent Title: FINELY DIVIDED, STARCH-CONTAINING POLYMER DISPERSIONS, PROCESSES FOR THEIR PREPARATION AND USE AS SIZES IN PAPERMAKING
  • Patent Title (中): 精细分散,含淀粉的聚合物分散体,其制备方法和用于造纸中的尺寸
  • Application No.: US14959118
    Application Date: 2015-12-04
  • Publication No.: US20160083909A1
    Publication Date: 2016-03-24
  • Inventor: Carmen-Elena CimpeanuHolger KernPetra ArnoldChristoph Hamers
  • Applicant: BASF SE
  • Applicant Address: DE Ludwigshafen
  • Assignee: BASF SE
  • Current Assignee: BASF SE
  • Current Assignee Address: DE Ludwigshafen
  • Priority: EP11185268.7 20111014
  • Main IPC: D21H21/16
  • IPC: D21H21/16 D21H19/20
FINELY DIVIDED, STARCH-CONTAINING POLYMER DISPERSIONS, PROCESSES FOR THEIR PREPARATION AND USE AS SIZES IN PAPERMAKING
Abstract:
A finely divided, starch-containing polymer dispersion which is obtainable by free radical emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one redox initiator and starch, wherein (a) from 0 to less than 40% by weight of at least one optionally substituted styrene, (b) from greater than 60 to 100% by weight of at least one C1-C12-alkyl acrylate and/or C1-C12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer, are used as the ethylenically unsaturated monomers, the sum (a)−(b)+(c) being 100% and being based on the active monomer content and (d) from 15 to 40% by weight of at least one degraded starch which has a molar mass Mw of from 1000 to 65 000 g/mol, based on the total weight of solids content of components (a)+(b)+(c)+(d), are used as the starch, and the polymerization being carried out in the presence of at least 0.01% by weight, based on the monomers used, of at least one terpene containing chain-transfer agent, and in which the polymer dispersion optionally comprises an aluminium compound. The use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard is also claimed.
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