发明申请
US20160102061A1 BACKFUNCTIONALIZED IMIDAZOLINIUM SALTS AND NHC CARBENE-METAL COMPLEXES
有权
官能化的咪唑烷盐和NHC碳 - 金属复合物
- 专利标题: BACKFUNCTIONALIZED IMIDAZOLINIUM SALTS AND NHC CARBENE-METAL COMPLEXES
- 专利标题(中): 官能化的咪唑烷盐和NHC碳 - 金属复合物
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申请号: US14880147申请日: 2015-10-09
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公开(公告)号: US20160102061A1公开(公告)日: 2016-04-14
- 发明人: Rusty L. Blanski , Robert H. Grubbs
- 申请人: Government of the United States as Represented by the Secretary of the Air Force
- 申请人地址: US OH Wright-Patterson AFB
- 专利权人: Government of the United States as Represented by the Secretary of the Air Force
- 当前专利权人: Government of the United States as Represented by the Secretary of the Air Force
- 当前专利权人地址: US OH Wright-Patterson AFB
- 主分类号: C07D233/28
- IPC分类号: C07D233/28 ; C07F15/00
摘要:
Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.