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公开(公告)号：US10538494B2
公开(公告)日：2020-01-21
申请号：US16103267
申请日：2018-08-14
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each selected from the group consisting of a C1-C20 alkyl group, C1-C20 partially fluorinated alkyl group, an aryl group, an aryl group with para CF3 functionality, an aryl group having C1-C20 partially fluorinated alkyl groups or partially fluorinated alkoxy groups, and a C1-C20 partially fluorinated aliphatic group, and a C1-C20 aryl group; and X is an anion. The method comprises cyclization of a halogenated acrylate with a formamidine with Hünig's base in a solvent.
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公开(公告)号：US20180370920A1
公开(公告)日：2018-12-27
申请号：US16103267
申请日：2018-08-14
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
CPC分类号： C07D233/28 , C07F15/0033 , C07F15/0046
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each selected from the group consisting of a C1-C20 alkyl group, C1-C20 partially fluorinated alkyl group, an aryl group, an aryl group with para CF3 functionality, an aryl group having C1-C20 partially fluorinated alkyl groups or partially fluorinated alkoxy groups, and a C1-C20 partially fluorinated aliphatic group, and a C1-C20 aryl group; and X is an anion. The method comprises cyclization of a halogenated acrylate with a formamidine with Hünig's base in a solvent.
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公开(公告)号：US10981878B2
公开(公告)日：2021-04-20
申请号：US16548444
申请日：2019-08-22
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US20200002286A1
公开(公告)日：2020-01-02
申请号：US16548419
申请日：2019-08-22
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US10913723B2
公开(公告)日：2021-02-09
申请号：US16548501
申请日：2019-08-22
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US20170247333A1
公开(公告)日：2017-08-31
申请号：US15596780
申请日：2017-05-16
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
CPC分类号： C07D233/28 , C07F15/0033 , C07F15/0046
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US20200002289A1
公开(公告)日：2020-01-02
申请号：US16548501
申请日：2019-08-22
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US20200002288A1
公开(公告)日：2020-01-02
申请号：US16548472
申请日：2019-08-22
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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公开(公告)号：US20180072681A1
公开(公告)日：2018-03-15
申请号：US15725848
申请日：2017-10-05
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
CPC分类号： C07D233/28 , C07F15/0033 , C07F15/0046
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
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10.发明申请公开(公告)号：US20160102061A1
公开(公告)日：2016-04-14
申请号：US14880147
申请日：2015-10-09
发明人： Rusty L. Blanski , Robert H. Grubbs
IPC分类号： C07D233/28 , C07F15/00
CPC分类号： C07D233/28 , C07F15/0033 , C07F15/0046
摘要： Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.
摘要翻译： 回归功能化的咪唑啉鎓盐及其合成方法和由其制备的NHC卡宾 - 金属络合物。 对于下式的后官能化咪唑啉鎓盐：其中R1选自酯基，酰胺基和芳族基团; R2选自氢，酯基，酰胺基和芳族基; R3和R4各自为脂族基团; X为阴离子; 该方法包括在溶剂中将Hünig碱卤化丙烯酸酯环化。
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