A die casting apparatus (100) for amorphous alloy and a method of die casting amorphous alloy may be provided. The die casting apparatus may comprise a stationary die (1) and a movable die (2); a sealed cabin (4) defining a sealing chamber (40); a protecting gas supplying device connected with the sealed cabin (4) for supplying the protecting gas into the sealing chamber (40); a melting device (5) for receiving and melting amorphous alloy; a feed sleeve (6) having a molten material inlet (60), with a plunger (7) positioned therein for injecting the molten amorphous alloy from the melting device (5) into a die chamber via the molten material inlet (60); a driving device (8) connected with the plunger (7) for driving the plunger (7) in the feed sleeve (6); and a gas purifying device (10) communicated with the sealed cabin (4) for purifying the gas from the sealed cabin (4).