Invention Application
- Patent Title: STABILIZED LITHIUM METAL FORMATIONS COATED WITH A SHELL CONTAINING NITROGEN, AND A METHOD FOR THE PRODUCTION OF SAME
- Patent Title (中): 用含氮壳包覆的稳定的锂金属成型品及其制造方法
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Application No.: US14785237Application Date: 2014-04-17
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Publication No.: US20160121396A1Publication Date: 2016-05-05
- Inventor: Ulrich WIETELMANN , Christoph HARTNIG , Ute EMMEL , Vera NICKEL
- Applicant: ROCKWOOD LITHIUM GMBH
- Priority: DE102013006724.3 20130419
- International Application: PCT/EP2014/057886 WO 20140417
- Main IPC: B22F1/00
- IPC: B22F1/00 ; H01M4/36 ; H01M4/62 ; H01M4/38

Abstract:
The invention relates to particulate lithium metal formations having a substantially spherical geometry and a core composed of metallic lithium, which are enclosed with an outer passivating but ionically conductive layer containing nitrogen. The invention further relates to a method for producing lithium metal formations by reacting lithium metal with one or more passivating agent(s) containing nitrogen, selected from the groups N2, NxHy with x=1 or 2 and y=3 or 4, or a compound containing only the elements C, H, and N, and optionally Li, at temperatures in the range between 60 and 300° C., preferably between 100 and 280° C., and particularly preferably above the melting temperature of lithium of 180.5° C., in an inert organic solvent under dispersion conditions or in an atmosphere that contains a gaseous coating agent containing nitrogen.
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