A monitoring system for charging of a super capacitor, comprising three parts, i.e. a power line, monomer super capacitor monitoring subsystems and a master monitoring system, wherein the master monitoring system comprises a charging circuit (2), a power supply unit (7), a master single chip microcomputer (4), a carrier communication module (3), a human-machine interface module (5), a storage unit (6) and an RS-232 module (8); and each of the monomer super capacitor monitoring subsystems comprises a monomer super capacitor (1), a power supply unit (7), a slave single chip microcomputer (11), a carrier communication module (3), a voltage, current and temperature detection unit (9) and a storage unit (6). The master monitoring system charges a super capacitor group through the power line and the charging circuit. The monitoring system can control the charge states of various monomer super capacitors, thereby avoiding the occurrence of an over-charging phenomenon.