A semiconductor process includes the following steps. A dielectric layer having a recess is formed on a substrate. A barrier layer is formed to cover the recess, thereby the barrier layer having two sidewall parts. A conductive layer is formed on the barrier layer by an atomic layer deposition process, thereby the conductive layer having two sidewall parts. The two sidewall parts of the conductive layer are pulled down. A conductive material fills the recess and has a part contacting the two sidewall parts of the barrier layer protruding from the two sidewall parts of the conductive layer, wherein the equilibrium potential difference between the barrier layer and the conductive layer is different from the equilibrium potential difference between the barrier layer and the conductive material. Moreover, the present invention also provides a semiconductor structure formed by said semiconductor process.