Invention Application
US20160346768A1 PROCESS FOR PREPARING A MULTIELEMENT OXIDE COMPRISING BISMUTH AND TUNGSTEN BY COPRECIPITATION
审中-公开
通过共混制备包含双相和多晶硅的多元氧化物的方法
- Patent Title: PROCESS FOR PREPARING A MULTIELEMENT OXIDE COMPRISING BISMUTH AND TUNGSTEN BY COPRECIPITATION
- Patent Title (中): 通过共混制备包含双相和多晶硅的多元氧化物的方法
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Application No.: US15164097Application Date: 2016-05-25
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Publication No.: US20160346768A1Publication Date: 2016-12-01
- Inventor: Stefan Wrobel , Wolfgang Hellerich , Cathrin Alexandra Welker-Nieuwoudt , Cornelia Katharina Dobner
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen am Rhein
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen am Rhein
- Priority: DE102015209638.6 20150527
- Main IPC: B01J23/888
- IPC: B01J23/888 ; B01J35/02 ; B01J37/00 ; B01J37/08 ; B01J23/31 ; B01J37/03

Abstract:
Shaped catalyst bodies comprising a multielement oxide I having the general stoichiometry I [Bi1WbOx]a[Mo12Z1cZ2dFeeZ3fZ4gZ5hOy]1 (I), where Z1=Ni or Co, Z2=alkali metal or alkaline earth metal, Z3=zinc, phosphorus, arsenic, boron, antimony, tin, cerium, vanadium, chromium or bismuth, Z4=silicon, aluminum, titanium, tungsten or zirconiurn, Z5=copper, silver, gold, yttrium, lanthanum and lanthanides, a=0.1 to 3, b=0.1 to 10, c=1 to 10, d=0.01 to 2, e=0.01 to 5, f=0 to 5, g=0 to 10, h=0 to 1 and x, y=numbers determined by the valence and abundance of the elements other than oxygen in I, as active composition are produced by preforming a mixed oxide Bi1WbOx by coprecipitation from an aqueous environment at a pH in the range from 1.5 to 3 and isolation of the precipitate by means of a mechanical separation process and mixing the preformed mixed oxide Bi1WbOx with a precursor having the stoichiometry [Mo12Z1cZ2dFeeZ3fZ4gZ5hOy], shaping the mixture to form shaped bodies and thermally treating and calcining the shaped bodies at elevated temperature to give the shaped catalyst bodies. The process leads to homogeneous precipitation products having a stoichiometric composition. It is an alternative to the energy-intensive production by spray drying.
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