A stacked-type solid electrolytic capacitor package structure includes a capacitor unit, a package unit, and a conductive unit. The capacitor unit includes a plurality of first stacked-type capacitors sequentially stacked on top of one another, and each first stacked-type capacitor has a first positive portion and a first negative portion. The package unit includes a package resin body for enclosing the capacitor unit. The conductive unit includes a first conductive terminal and a second conductive terminal. The first conductive terminal has a first embedded portion and a first exposed portion, and the second conductive terminal has a second embedded portion and a second exposed portion. An outermost one of first stacked-type capacitors has a plurality of first exposed soldering microgrooves formed on an outer surface thereof for contacting the package resin body. The instant disclosure further provides a method of manufacturing a stacked-type solid electrolytic capacitor package structure.