A reverse electrodialysis device, including an anode, a cathode, one or more single cells spaced apart from each other between the anode and the cathode, each single cell including a cation exchange membrane and an anion exchange membrane, and a shielding membrane disposed to define spaces between the anode and the single cell and/or between the cathode and the single cell. The cation exchange membrane and the shielding membrane include a porous polymer substrate and a polymer electrolyte incorporated into pores in the substrate.