发明申请
- 专利标题: ACTIVATION OF SUPPORTED OLEFIN METATHESIS CATALYSTS BY ORGANIC REDUCTANTS
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申请号: US15536446申请日: 2015-12-15
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公开(公告)号: US20170348681A1公开(公告)日: 2017-12-07
- 发明人: Christophe Coperet , Victor Mougel , Kazushi Mashima , Hayato Tsurugi , Haruki Nagae
- 申请人: ETH Zurich , Osaka University
- 优先权: EP14004251.6 20141217; EP15002559.1 20150831
- 国际申请: PCT/CH2015/000185 WO 20151215
- 主分类号: B01J31/16
- IPC分类号: B01J31/16 ; C07C67/465 ; C07C6/06 ; C07C6/04 ; B01J37/16
摘要:
An organic reductant, in particular an organo silicon reductant suitable for activating supported catalysts of the type MOnEm, wherein E is S and/or Se, in particular MOn, wherein M is W, Mo or Re, is described as well as its use in metathesis reactions. The reduced catalysts are able to metathesize olefins at low temperatures and are therefore also suitable for metathesis of functionalized olefins.
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