- 专利标题: CLOSED REACTOR TRANSITIONS BETWEEN METALLOCENE CATALYSTS
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申请号: US15564456申请日: 2016-04-06
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公开(公告)号: US20180079836A1公开(公告)日: 2018-03-22
- 发明人: Brandon C. Locklear , R. Eric Pequeno , Richard B. Pannell , Fathi David Hussein , Rich John Stolz , William A. Matthews
- 申请人: Univation Technologies, LLC
- 申请人地址: US TX Houston
- 专利权人: Univation Technologies, LLC
- 当前专利权人: Univation Technologies, LLC
- 当前专利权人地址: US TX Houston
- 国际申请: PCT/US2016/026201 WO 20160406
- 主分类号: C08F2/34
- IPC分类号: C08F2/34 ; C08F2/38 ; C08F110/02 ; C08F4/6592 ; B01J8/18
摘要:
A method for transitioning a gas phase polymerization reactor between metallocene catalysts is provided. The method comprises first reducing the superficial gas velocity and increasing the height of the fluidized bed within the reactor prior to stopping a feed comprising a first metallocene catalyst. The method further comprises introducing a first polymerization neutralizer to the reactor, wherein the first polymerization reactor does not comprise water, and then introducing a second polymerization neutralizer to the reactor, wherein the second polymerization neutralizer is different from the first polymerization neutralizer. After this, the method comprises purging the reactor with an inert gas and then introducing a feed comprising a second metallocene catalyst to the reactor.
公开/授权文献
- US10221254B2 Closed reactor transitions between metallocene catalysts 公开/授权日:2019-03-05
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