A lightweight flexible BNNT mat or fabric provides improved thermal stability and shielding capabilities under a hypersonic thermal flux. The BNNT mat reduces the stagnation temperature and maintains a low regression rate. An in-situ passivation layer may be formed on the BNNT mat or fabric under high thermal flux. The passivation layer minimizes or prevents penetration of the atmosphere (air or gas) as well as heat and radiation through the thickness of the BNNT material, and it effectively diffuses heat throughout the mat or fabric laterally and radially to minimize localized excessive heat. A BNNT mat according to the present disclosure may also efficiently transfer heat from the BNNT material via radiation due to the high thermal emissivity (0.92) of the BNNT material.