Processes for co-production of methyl tertiary-butyl ether (MTBE) and alkylate is disclosed. The process includes comprising passing a hydrocarbon feed stream comprising C4 hydrocarbons to a dehydrogenation unit to generate a dehydrogenation effluent comprising C4 olefins. The dehydrogenation effluent is passed to a MTBE unit to provide a mixed stream comprising C4 olefins and MTBE. The mixed stream is separated to provide an MTBE product stream and a fractionator overhead stream comprising olefins. The fractionator overhead stream is passed to an alkylation unit to produce an alkylation product stream comprising an alkylate.