- 专利标题: PROCESS FOR PRODUCING ACETIC ACID
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申请号: US16265535申请日: 2019-02-01
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公开(公告)号: US20190263744A1公开(公告)日: 2019-08-29
- 发明人: Masahiko SHIMIZU , Yoshihisa MIZUTANI , Hiroyuki MIURA
- 申请人: Daicel Corporation
- 申请人地址: JP Osaka-shi,
- 专利权人: Daicel Corporation
- 当前专利权人: Daicel Corporation
- 当前专利权人地址: JP Osaka-shi,
- 优先权: JP2017-020775 20170207; JP2017-105771 20170529
- 主分类号: C07C51/44
- IPC分类号: C07C51/44 ; B01D15/36 ; C07C51/12 ; C07C51/47 ; B01D3/14 ; B01J27/08 ; B01J31/02
摘要:
A process for producing acetic acid comprises a process comprising: (1) carbonylating methanol; (2) separating the reaction mixture into a volatile phase and a less-volatile phase; (3) distilling the volatile phase to forma first overhead rich in a lower boiling component, and an acetic acid stream rich in acetic acid; and at least one step group selected from the group consisting of the following sections (4), (9), and (15): (4) a section for separating impurities from the acetic acid stream to give purified acetic acid, (9) a section for separating the first overhead into a stream rich in acetaldehyde and a stream rich in methyl iodide, and (15) a section for absorption-treating an off-gas from the process with an absorption solvent and forming a carbon monoxide-rich stream and an acetic acid-rich stream. In this process, the concentration of oxygen in a gaseous phase of the process is controlled to less than 7% by volume and/or the concentration of oxygen in a liquid phase of the process is controlled to less than 7×10−5 g/g, and the formation of iodine is reduced. The process effectively reduces or prevents local corrosion of an inner wall of a process unit and/or line.
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