- 专利标题: METHOD AND DEVICE FOR CARRYING OUT ENDOTHERMIC GAS PHASE-SOLID OR GAS-SOLID REACTIONS
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申请号: US16346672申请日: 2017-10-26
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公开(公告)号: US20200061565A1公开(公告)日: 2020-02-27
- 发明人: Grigorios KOLIOS , Bernd ZOELS , Matthias KERN , Jens BERNNAT , Rene KOENIG , Friedrich GLENK , Achim WECHSUNG
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen am Rhein
- 优先权: EP16197338.3 20161104
- 国际申请: PCT/EP2017/077433 WO 20171026
- 主分类号: B01J6/00
- IPC分类号: B01J6/00 ; B01J8/04 ; C01B32/05 ; C01B3/26 ; C01B3/38 ; C01B3/04 ; C01B13/02 ; C04B2/10 ; C01F7/44 ; C10G9/00 ; C07C5/333 ; C07C5/41
摘要:
The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.
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