An apparatus for combustion optimization is provided. The apparatus for combustion optimization includes a management layer configured to collect currently measured real-time data for boiler combustion, and to determine whether to perform combustion optimization and whether to tune a combustion model and a combustion controller by analyzing the collected real-time data, a data layer configured to derive learning data necessary for designing the combustion model and the combustion controller from the real-time data and previously measured past data for the boiler combustion, a model layer configured to generate the combustion model and the combustion controller through the learning data, and an optimal layer configured to calculate a target value for the combustion optimization by using the combustion model and the combustion controller, and to output a control signal according to the calculated target value.