- 专利标题: PROCESS FOR PREPARING AN ANTICORROSION COMPONENT FOR AN ANTIFREEZE
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申请号: US16494970申请日: 2018-03-06
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公开(公告)号: US20200283365A1公开(公告)日: 2020-09-10
- 发明人: Nicolas VAUTRAVERS , Joaquim Henrique TELES , Henning ALTHOEFER , Harald DIETL
- 申请人: BASF SE
- 优先权: com.zzzhc.datahub.patent.etl.us.BibliographicData$PriorityClaim@796a97f0
- 国际申请: PCT/EP2018/055443 WO 20180306
- 主分类号: C07C51/235
- IPC分类号: C07C51/235 ; C09K5/20 ; C23F11/12
摘要:
A process for preparing an anticorrosion component for an antifreeze by oxidizing an oxydiol (I) in which x is 0 (zero) or a positive integer from 1 to 10 with molecular oxygen at a temperature of 20 to 100° C. and a partial oxygen pressure of 0.01 to 2 MPa in the presence of water and of a heterogeneous catalyst comprising platinum to form an oxydicarboxylic acid (II) in which y is 0 (zero) or a positive integer from 1 to 10, in which the oxidation is conducted (a) at a molar ratio of 0.002≤n(Pt)/[n(oxydiol (I))+n(oxydicarboxylic acid (II))]≤0.019 where “n(Pt)” Is the molar amount of platinum, “n(oxydiol (I))” is the molar amount of oxydiol (I) and “n(oxydicarboxylic acid (II))” Is the molar amount of oxydicarboxylic acid (II); (b) at a concentration of water of 50% to 95% by weight in the liquid phase; and (c) at a pH of 1 to 7.
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