摘要:
A process for preparing an anticorrosion component for an antifreeze by oxidizing an oxydiol (I) in which x is 0 (zero) or a positive integer from 1 to 10 with molecular oxygen at a temperature of 20 to 100° C. and a partial oxygen pressure of 0.01 to 2 MPa in the presence of water and of a heterogeneous catalyst comprising platinum to form an oxydicarboxylic acid (II) in which y is 0 (zero) or a positive integer from 1 to 10, in which the oxidation is conducted (a) at a molar ratio of 0.002≤n(Pt)/[n(oxydiol (I))+n(oxydicarboxylic acid (II))]≤0.019 where “n(Pt)” Is the molar amount of platinum, “n(oxydiol (I))” is the molar amount of oxydiol (I) and “n(oxydicarboxylic acid (II))” Is the molar amount of oxydicarboxylic acid (II); (b) at a concentration of water of 50% to 95% by weight in the liquid phase; and (c) at a pH of 1 to 7.
摘要:
A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200° C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).
摘要:
A process for preparing ethene oxide comprising providing a liquid feed stream comprising ethene, hydrogen peroxide, and a solvent; passing the liquid feed stream into an epoxidation zone comprising a catalyst comprising a titanium zeolite comprising zinc and having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising ethene oxide, water, and the solvent; removing an effluent stream from the epoxidation zone, the effluent stream comprising ethene oxide, water and the solvent.
摘要:
Use of an acid-treated titanium-containing zeolitic material having framework type MWW for preparing a composition having a relative plasticity of less than 1.
摘要:
Disclosed herein is a process for purifying propylene oxide, including the steps of: (i) providing a stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing a carbonyl group —C(═O)—; and (ii) separating propylene oxide from the stream S0 by subjecting the stream S0 to distillation conditions in a distillation column to obtain a gaseous top stream S1c which is enriched in propylene oxide compared to the stream S0, a liquid bottoms stream S1a which is enriched in acetonitrile and water compared to the stream S0, and a side stream S1b containing propylene oxide which is enriched in the carbonyl compound compared to the stream S0.
摘要:
The invention relates to process for the regeneration of a catalyst comprising a titanium containing zeolite as catalytically active material comprising a stage comprising introducing a feed stream comprising propene, hydrogen peroxide or a hydrogen peroxide source, and an organic solvent into a reactor containing a catalyst comprising the titanium containing zeolite, subjecting the feed stream in the reactor to epoxidation conditions in the presence of the catalyst, removing a product steam comprising propylene oxide and the organic solvent from the reactor, stopping introducing the feed stream, washing the catalyst with a liquid aqueous system and calcining the washed catalyst.
摘要:
The present invention relates to the use of hexadeca-8,15-dienal or of a substance mixture which comprises this compound as aroma chemical, in particular as fragrance, or formulation auxiliary; and also to processes for its preparation, moreover aroma substance compositions and compositions comprising hexadeca-8,15-dienal.
摘要:
The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two- or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.
摘要:
The invention relates to a process for preparing nitroalkanes by reaction of at least one alkane with at least one nitrating agent in the gas phase, wherein the nitration is carried out in a microstructured reaction zone having parallel channels having hydraulic diameters of less than 2.5 mm and a total specific internal surface area of more than 1600 m2/m3 and the alkane and the nitrating agent are conveyed under a pressure of from 1 bar to 20 bar through the reaction zone and reacted at a temperature of from 150° C. to 650° C. and the reaction products are cooled downstream of the reaction zone and discharged and the at least one nitrating agent is introduced over from two to ten introduction points along the reaction zone.
摘要翻译:本发明涉及通过在气相中至少一种烷烃与至少一种硝化剂反应来制备硝基烷烃的方法,其中硝化在具有水力直径小于2.5mm的平行通道的微结构反应区中进行,以及 超过1600m 2 / m 3的总比表面积和烷烃和硝化剂在1巴-20巴的压力下通过反应区输送,并在150℃至650℃的温度下反应 并且反应产物在反应区的下游冷却并排出,并且将至少一种硝化剂沿着反应区引入二至十个引入点。
摘要:
A container and a process for the degradation stable storage and transport of a liquid comprising a saturated aliphatic C6-12 carboxylic acid in which the liquid is covered with an oxygen free or at least heavily oxygen depleted inert gas phase atmosphere above the liquid.