This invention relates to a novel conductive organic membrane-coupled filtration system for the degradation of organic pollutants from wastewater. The system comprises a connected water pump and a reactor. The upper end of the reactor contained a water inlet, and the lower end consisted of a water outlet. A counter electrode and a membrane electrode are fixed on the reactor between the water inlet and water outlet. The counter electrode and membrane electrode constitute a two-electrode system connected to an external potentiostat through metal wires. The membrane electrode is made of carbon-based polyvinylidene fluoride (PVDF) membrane that can be used to enhance the electrochemical separation of small molecules and the removal of organic pollutants.