The present disclosure provides a prelithiation solution for a graphite or graphite/silicon composite anode, which includes: (a) a cyclic or linear ether-based solvent; and (b) an aromatic hydrocarbon-lithium complex, and has a reduction potential of 0.25 V (vs Li/Li+) or lower.
According to the present disclosure, lithium ions can be chemically intercalated uniformly throughout a graphite or graphite composite anode in solution phase and a high level of prelithiation may be achieved. In addition, an anode having an initial coulombic efficiency close to 100% may be provided by prelithiating a graphite or graphite composite anode using the prelithiation solution and a commercially applicable lithium secondary battery exhibiting high energy density may be provided based thereon.