Presented herein are techniques to facilitate extending a multiple access Protocol Data Unit (PDU) session and Access Traffic Steering, Switching, and Splitting Low-Layer (ATSSS-LL) policies to an enterprise network. In one example, a method may include obtaining a request for an ATSSS-LL policy for a user equipment (UE) for establishing a multiple access protocol data unit session for the UE via a wireless wide area access network for an enterprise network; and providing to the UE one or more ATSSS-LL rules for the ATSSS-LL policy, an Internet Protocol (IP) address for the multiple access protocol data unit session for the UE, and an identifier for the multiple access protocol data unit session for the UE in which the IP address is utilized for a wireless local area access network connection for the UE established via a wireless local area access network of the enterprise network.